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Thus, for the pro le data presented in the table, = 89 and VL = 1.58. The interpretive signi cance of vector angle and vector length for pro le description has been explored extensively in the interpersonal literature (e.g., Gurtman & Balakrishnan, 1998; Leary, 1957; Wiggins et al., 1989), but not more generally. Computationally, the angle is the circular mean of the pro le (Mardia, 1972), indicating what may be construed as the center of gravity (Gurtman & Balakrishnan, 1998) of the pro le distribution. It thus points to the predominant theme of the pro le (Gurtman & Balakrishnan, 1998), the blend of the two dimensions that underlie the particular circumplex domain. For example, when based on the interpersonal circumplex, the person s vector angle may be interpreted in terms of the individual s standing on two major dimensions of the interpersonal domain (generally Dominance and Nurturance; e.g., see Wiggins & Trapnell, 1996). For vocational interests, as in the present example, the circumplex is anchored by two RIASEC dimensions (Prediger, 1982): interests in People versus Things (vertical axis) and Data versus Ideas (horizontal axis). The case s obtained angle of 89 (between Helping and Social Facilitating on the circle) suggests a relatively pure interest theme of People as a summary of the overall pattern. Turning to vector length, this summary feature is sometimes thought of as a measure of pro le extremity or intensity (e.g., Kiesler, 1996). We regard vector length as more a measure of pro le de nition, or, as is stated later, structured patterning (Gurtman & Balakrishnan, 1998). High vector length indicates a well-articulated pro le, with a clear central tendency or directional trend (as in the present case); low vector length suggests poor de nition, generally due to low

The authors would like to thank the members of the EFPPA Task Force on Health Psychology (convenor: David F. Marks): Carola Brucher-Albers, Berufsverband Deutscher Psychologen e.V.; Frank J. S. Donker, Nederlands Institut van Psychogen; Zenia Jepsen, Dansk Psykologforening; Jesus Rodriguez-Marin, Colegio O cial de Psicologos; Sylvaine Sidot, Association Nationale des Organizations de Psychologues; Brit Wallin Backman, Norsk Psykologforening. Sections of this chapter are adapted from the Task Force report (Marks et al., 1998).

RACE/ETHNICITY 546 African Americans 546 Asian Americans/Paci c Islanders 547 Latino(a) Americans 548 Native Americans 550 Behavioral Treatment and Prevention Approaches for Ethnic Minorities 551 GENDER 552 Biological Factors 552 Behavioral Factors 553 Psychosocial Factors 553 Biobehavioral Factors 554 Gender, Treatment, and Prevention Approaches 554

substances These substances may act as inhibitors of S(IV) oxidation processes, distorting the expected pathways of the reaction, as well as the yield and distribution of reaction products They may react with sulphur-oxy radicals [107] and/or TMI [93, 96, 108] Up to now, the following organic compounds were found as effective inhibitors of S(IV) oxidation: phenols [109], alcohols [110], benzene [95], toluene, naphthalene and paraf n oil [103], terpenes [107] and carboxylic acids [93, 96, 108, 111] Oxalate has a strong inhibiting effect on the iron-catalysed S(IV) oxidation [93, 96, 108, 112] The formation of stable complexes with Fe(III) (see Section 5223) affects the redox cycling of Fe(II)/Fe(III) and thus the reaction rate By online measurements of the redox cycling of Fe(II)/Fe(III) (pH = 28, 37 and 45) during the reaction course, Grgi et al.

[93] c demonstrated that the presence of oxalate increases the concentration of dissolved Fe(III), while on the other hand it prevents the reduction of Fe(III) The formation of Fe(III) oxalato complexes competes with the formation of Fe(III) sulphito complexes, that is the rst step of a radical chain mechanism (Table 52, reaction 1) Therefore, the concentration of Fe(II) formed from catalytically active Fe(III) species after the reduction with HSO decreases with increasing 3 concentration of oxalate (Figure 59a) It was also shown that the effect of oxalate on the redox cycling of iron and thus on the reaction rate differs according to whether iron is initially present as Fe(III) or Fe(II) [96] (Figure 59) In the case of Fe(II) (Figure 59b), an induction period appears during which Fe(III) is formed and immediately complexed with oxalate.

VoIP IMPLEMENTATION CHALLENGES The openness and exibility of the IP and the World Wide Web (WWW) have steered the development of a variety of devices and techniques for implementation of VoIP. However, the same openness, ubiquity, and exibility to support open APIs and to carry multiple types of tra c (e.g., real- and non-realtime audio, video, and data streams) have also created many service reliability and security related concerns. Some of these issues are discussed below, along with a few desirable features of the feasible solutions.

Consequently, the equilibrium between the Fe(III) oxalato complexes and free Fe(III) depends upon the concentration of oxalate When the equilibrium is reached, free Fe(III) initiates the reaction and the concentration of Fe(II) sharply decreases to the value that corresponds to the concentration of Fe(II) formed after the reduction of catalytically active Fe(III) Carboxylates like acetate and formate, which are not strong complex formers, have also been shown to have an inhibiting effect on the iron-catalysed S(IV) oxidation at pH higher than 4 [93, 111] However their effect is much lower in comparison to the effect of oxalate The in uence of carboxylic acids on the oxidation of S(IV) catalysed by Mn(II) under conditions representative for tropospheric liquid water was also investigated [113] Among the monocarboxylic acids (formic, glycolic, lactic and acetic) formic acid was found to have the strongest inhibiting effect.

The results suggest that the most probable reason for the inhibition is the interaction between sulphate radicals and carboxylic acids, that is scavenging of sulphate radicals Oxalic acid has also been shown to slow down the Mn(II)-catalysed oxidation of S(IV); however, its in uence is much lower than the in uence of monocarboxylic acids as well as its in uence on iron catalytic reaction..